Others
Product classification
Contact us
Factory sells 1,4,7-tris[(4-Methylphenyl)sulfonyl]-1,4,7-triazonane 52667-89-7 with sufficient production capacity
- Molecular Formula: C27H33N3O6S3
- Molecular Weight: 591.774
- Vapor Pressure: 0mmHg at 25°C
- Melting Point: 222-224℃
- Boiling Point: 749.407oC at 760 mmHg
- PKA: -7.08±0.20(Predicted)
- Flash Point: 407.027oC
- PSA： 137.28000
- Density: 1.334g/cm3
- LogP: 6.05400
1,4,7-tris[(4-Methylphenyl)sulfonyl]-1,4,7-triazonane(Cas 52667-89-7) Usage
|
General Description |
1,4,7-tris[(4-Methylphenyl)sulfonyl]-1,4,7-triazonane is a chemical compound with the molecular formula C24H30N4O6S3. It is a complex structure consisting of three sulfonyl groups attached to a triazonane ring. 1,4,7-tris[(4-Methylphenyl)sulfonyl]-1,4,7-triazonane falls under the category of triazinanes, which are heterocyclic organic compounds containing nitrogen in the ring. The presence of the sulfonyl groups suggests that this chemical may have various uses in organic synthesis, potentially serving as a building block for the creation of other more complex compounds. Overall, 1,4,7-tris[(4-Methylphenyl)sulfonyl]-1,4,7-triazonane is a significant molecule with potential applications in various fields, including pharmaceuticals, materials science, and chemical research. |
InChI:InChI=1/C27H33N3O6S3/c1-22-4-10-25(11-5-22)37(31,32)28-16-18-29(38(33,34)26-12-6-23(2)7-13-26)20-21-30(19-17-28)39(35,36)27-14-8-24(3)9-15-27/h4-15H,16-21H2,1-3H3
52667-89-7 Relevant articles
Reusable and environmentally friendly ionic trinuclear iron complex catalyst for atom transfer radical polymerization
Niibayashi, Shota,Hayakawa, Hitoshi,Jin, Ren-Hua,Nagashima, Hideo
, p. 1855 - 1857 (2007)
Ionic iron complex [(Me3tacn)2Fe2Cl 3]+[...
A Bis-Triazacyclononane Tris-Pyridyl N9-Azacryptand “Beer Can” Receptor for Complexation of Alkali Metal and Lead(II) Cations
Brown, Asha,Bunchuay, Thanthapatra,Crane, Christopher G.,White, Nicholas G.,Thompson, Amber L.,Beer, Paul D.
, p. 10434 - 10442 (2018)
A new bis-triazacyclononane tris-pyridyl...
Paramagnetic palladacycles with PdIII centers are highly active catalysts for asymmetric aza-Claisen rearrangements
Eitel, Simon H.,Bauer, Matthias,Schweinfurth, David,Deibel, Naina,Sarkar, Biprajit,Kelm, Harald,Krueger, Hans-Joerg,Frey, Wolfgang,Peters, Rene
, p. 4683 - 4693 (2012)
A combination of spectroscopic and elect...
DINUCLEATING LIGAND OR DINUCLEAR METAL COMPLEX
-
Paragraph 0048; 0052-0053, (2021/03/19)
To provide a dinuclear metal complex tha...
Second-Sphere Interaction Promoted Turn-On Fluorescence for Selective Sensing of Organic Amines in a TbIII-based Macrocyclic Framework
Huang, Xianqiang,Liu, Qingzhi,Liu, Shixi,Ma, Shengqian,Nafady, Ayman,Niu, Zheng,Ren, Junyu,Tsai, Chen-Yen,Ye, Yingxiang
supporting information, p. 23705 - 23712 (2021/09/22)
Guided by a second-sphere interaction st...
METHOD FOR PREPARING NOTA DERIVATIVE
-
Paragraph 0024; 0032; 0038; 0040; 0047, (2019/09/20)
A method for preparing a NOTA derivative...
METHOD FOR PREPARING NOTA DERIVATIVE
-
, (2019/08/14)
The present invention discloses Method f...
52667-89-7 Process route
-
-
56187-04-3
1,4,7-tritosyl-1,4,7-triazaheptane
-
-
6315-52-2
1,2-bis-tosyloxyethane
-
-
52667-89-7
N,N',N-tris(p-toluenesulfonyl)-1,4,7-triazacyclononane
| Conditions | Yield |
|---|---|
|
1,4,7-tritosyl-1,4,7-triazaheptane;
With
caesium carbonate;
In
N,N-dimethyl-formamide;
at 20 ℃;
for 1.5h;
Inert atmosphere;
1,2-bis-tosyloxyethane;
In
N,N-dimethyl-formamide;
at 20 ℃;
for 48h;
Inert atmosphere;
|
96%
|
|
With
sodium hydride;
In
N,N-dimethyl-formamide; mineral oil;
at 90 ℃;
for 24h;
Cooling with ice;
Inert atmosphere;
Darkness;
|
94%
|
|
With
sodium hydride;
In
various solvents; N,N-dimethyl-formamide;
at 105 ℃;
for 8h;
|
87%
|
|
1,4,7-tritosyl-1,4,7-triazaheptane;
With
caesium carbonate;
In
N,N-dimethyl-formamide;
at 25 ℃;
for 1h;
Inert atmosphere;
1,2-bis-tosyloxyethane;
In
N,N-dimethyl-formamide;
at 20 ℃;
Inert atmosphere;
|
85%
|
|
1,4,7-tritosyl-1,4,7-triazaheptane;
With
caesium carbonate;
In
N,N-dimethyl-formamide;
at 25 ℃;
for 1h;
1,2-bis-tosyloxyethane;
In
N,N-dimethyl-formamide;
at 20 ℃;
|
85%
|
|
1,4,7-tritosyl-1,4,7-triazaheptane;
With
tetra(n-butyl)ammonium hydroxide; sodium hydroxide;
In
water; toluene;
at 90 ℃;
for 0.5h;
1,2-bis-tosyloxyethane;
In
water; toluene;
at 90 ℃;
for 8h;
|
81%
|
|
With
sodium hydroxide;
tetra-(n-butyl)ammonium iodide;
In
water; toluene;
Heating;
8-10 h;
|
80%
|
|
With
sodium hydride;
In
N,N-dimethyl-formamide;
at 105 ℃;
for 4.5h;
|
80%
|
|
With
potassium fluoride on basic alumina;
In
acetonitrile;
Heating;
|
75%
|
|
1,4,7-tritosyl-1,4,7-triazaheptane; 1,2-bis-tosyloxyethane;
With
sodium hydride;
In
N,N-dimethyl-formamide;
for 3h;
Heating;
In
N,N-dimethyl-formamide;
for 15h;
|
75%
|
|
With
sodium hydride;
Yield given. Multistep reaction;
1.) DMF, 2.) 105 deg C, 2 h;
|
|
|
With
sodium ethanolate;
Yield given. Multistep reaction;
1.) EtOH, overnight, 2.) DMF, 100 deg C, 1 h;
|
|
|
1,4,7-tritosyl-1,4,7-triazaheptane;
With
sodium ethanolate;
In
ethanol;
for 0.5h;
Reflux;
Inert atmosphere;
1,2-bis-tosyloxyethane;
In
N,N-dimethyl-formamide;
at 100 ℃;
for 0.5h;
Inert atmosphere;
|
2.28 g
|
|
With
caesium carbonate;
In
N,N-dimethyl-formamide;
at 20 ℃;
|
-
-
6315-52-2
1,2-bis-tosyloxyethane
-
-
52667-89-7
N,N',N-tris(p-toluenesulfonyl)-1,4,7-triazacyclononane
| Conditions | Yield |
|---|---|
|
In
N,N-dimethyl-formamide;
at 20 ℃;
|
86%
|
52667-89-7 Upstream products
-
56187-04-3
1,4,7-tritosyl-1,4,7-triazaheptane
-
6315-52-2
1,2-bis-tosyloxyethane
-
1074-82-4
potassium phtalimide
-
99142-40-2
Toluene-4-sulfonic acid 2-[(toluene-4-sulfonyl)-(2-{(toluene-4-sulfonyl)-[2-(toluene-4-sulfonylamino)-ethyl]-amino}-ethyl)-amino]-ethyl ester
52667-89-7 Downstream products
-
58966-93-1
1,4,7-triazacyclononane trihydrochloride
-
4730-54-5
1,4,7-triazacyclononane
-
129422-96-4
1-(p-toluenesulfonyl)-1,4,7-triazacyclononane
-
95388-08-2
N,N'-bis(p-toluenesulfonyl)-1,4,7-triazacyclononane
Related products
-
Mucopolysaccharides, glycosaminoglycans, chondroitin sulfate-dermatan sulfate-contg., skinDetail
CAS:94945-04-7
-
4-MethoxyindoleDetail
CAS:4837-90-5
-
8-bromo-7-(but-2-ynyl)-3-methyl-1H-purine-2,6(3H,7H)-dioneDetail
CAS:666816-98-4
- Detail