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(Z,E)-9,12-TETRADECADIENYLACETATE

  • CAS:30507-70-1
  • purity:99%
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Factory Supply Industrial Grade (Z,E)-9,12-TETRADECADIENYLACETATE 30507-70-1 with Best Price

  • Molecular Formula:C16H28 O2
  • Molecular Weight:252.397
  • Refractive Index:1.4565 (25℃) 
  • Boiling Point:334.8°Cat760mmHg 
  • Flash Point:102.3°C 
  • PSA:40.13000 
  • Density:0.89g/cm3 
  • LogP:3.76960 

30507-70-1 Relevant articles

Pheromones. IV: Stereoselective synthesis of (Z) 9, (E) 12 tetradecadienyl 1 acetate

Bestmann,Vostrowsky,Plenchette

, p. 779 - 780 (1974)

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Method for synthesizing (9Z, 12E)-9,12-tetradecadien-1-ol acetate

-

Paragraph 0011; 0042-0044, (2020/06/16)

The invention belongs to the technical f...

SYNTHESIS OF PHEROMONES AND RELATED MATERIALS VIA OLEFIN METATHESIS

-

Paragraph 0110, (2018/09/12)

Methods for preparation of olefins, incl...

Double-Bond Isomerization: Highly Reactive Nickel Catalyst Applied in the Synthesis of the Pheromone (9 Z,12 Z)-Tetradeca-9,12-dienyl Acetate

Weber, Felicia,Schmidt, Anastasia,R?se, Philipp,Fischer, Michel,Burghaus, Olaf,Hilt, Gerhard

supporting information, p. 2952 - 2955 (2015/06/30)

A highly reactive nickel catalyst compri...

SYNTHESIS OF Z-OLEFIN-CONTAINING LEPIDOPTERAN INSECT PHEROMONES

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Paragraph 0200; 0201, (2013/09/12)

The present invention is directed to met...

30507-70-1 Process route

9-acetoxynonal
29541-97-7

9-acetoxynonal

<(E)-3-Pentenyl>triphenylphosphonium-bromid
53143-96-7

<(E)-3-Pentenyl>triphenylphosphonium-bromid

Tetradec-9Z,12E-dien-1-yl Acetate
30507-70-1

Tetradec-9Z,12E-dien-1-yl Acetate

Conditions
Conditions Yield
<(E)-3-Pentenyl>triphenylphosphonium-bromid; With sodium hexamethyldisilazane; In tetrahydrofuran; at -78 ℃; for 1h; Inert atmosphere;
9-acetoxynonal; In tetrahydrofuran; at -78 - 20 ℃; for 24h; Inert atmosphere;
56%
<(E)-3-Pentenyl>triphenylphosphonium-bromid; With n-butyllithium; diisopropylamine; In tetrahydrofuran; hexane; at -20 ℃; for 1h;
9-acetoxynonal; In tetrahydrofuran; hexane; at -60 - 20 ℃; Further stages.;
54%
(E)-12-tetradec-9-yn-12-en-1-yl acetate
71394-01-9

(E)-12-tetradec-9-yn-12-en-1-yl acetate

Tetradec-9Z,12E-dien-1-yl Acetate
30507-70-1

Tetradec-9Z,12E-dien-1-yl Acetate

Conditions
Conditions Yield
With hydrogen; sodium tetrahydroborate; nickel diacetate; ethylenediamine; In ethanol; Ambient temperature;
85%
With quinoline; hydrogen; Lindlar's catalyst; In hexane; at -10 ℃;
55.5%
With hydrogen; P-2Ni;
With quinoline; hydrogen; Lindlar's catalyst; In hexane; at -10 ℃; Yield given;

30507-70-1 Upstream products

  • 29541-97-7
    29541-97-7

    9-acetoxynonal

  • 120593-09-1
    120593-09-1

    ((E)-Pent-3-enylidene)-triphenyl-λ5-phosphane

  • 112464-06-9
    112464-06-9

    1-<(tetrahydro-2H-pyran-2-yl)oxy> 9Z, 12E-tetradecadiene

  • 70654-44-3
    70654-44-3

    (Z,E)-9,12-tetradecadien-1-ol

30507-70-1 Downstream products

  • 42521-46-0
    42521-46-0

    Tetradeca-cis-9,trans-12-dien-1-ol

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