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Factory Sells Best Quality Benzyl (S)-(-)-tetrahydro-5-oxo-3-furanylcarbamate 87219-29-2 with USP
- Molecular Formula: C12H13NO4
- Molecular Weight: 235.24
- Vapor Pressure: 0mmHg at 25°C
- Melting Point: 103-105 °C(lit.)
- Refractive Index: 1.561
- Boiling Point: 466.087 °C at 760 mmHg
- PKA: 10.87±0.20(Predicted)
- Flash Point: 235.681 °C
- PSA： 64.63000
- Density: 1.272 g/cm3
- LogP: 1.61920
Benzyl (S)-(-)-tetrahydro-5-oxo-3-furanylcarbamate(Cas 87219-29-2) Usage
InChI:InChI=1/C12H13NO4/c14-11-6-10(8-16-11)13-12(15)17-7-9-4-2-1-3-5-9/h1-5,10H,6-8H2,(H,13,15)/t10-/m0/s1
87219-29-2 Relevant articles
Baeyer–Villiger monooxygenase-catalyzed desymmetrizations of cyclobutanones. Application to the synthesis of valuable spirolactones
Rodríguez-Mata, María,Lavandera, Iván,Gotor-Fernández, Vicente,Gotor, Vicente,García-Cerrada, Susana,Mendiola, Javier,de Frutos, óscar,Collado, Iván
supporting information, p. 7268 - 7275 (2016/10/26)
A series of γ-butyrolactone derivatives,...
Efficient and Selective Cu/Nitroxyl-Catalyzed Methods for Aerobic Oxidative Lactonization of Diols
Xie, Xiaomin,Stahl, Shannon S.
supporting information, p. 3767 - 3770 (2015/04/14)
Cu/nitroxyl catalysts have been identifi...
Studies towards the total synthesis of batzelladine A
Elliott, Mark C.,Long, Matthew S.
, p. 2003 - 2011 (2007/10/03)
Application of a diastereoselective thre...
β-Pseudopeptide foldamers. the homo-oligomers of (4R)-(2-oxo-1,3-oxazolidin-4-yl)-acetic acid (D-Oxac)
Luppi, Gianluigi,Galeazzi, Roberta,Garavelli, Marco,Formaggio, Fernando,Tomasini, Claudia
, p. 2181 - 2187 (2007/10/03)
A total synthesis in solution and a conf...
87219-29-2 Process route
-
![[(1S)-3-hydroxy-1-(hydroxymethyl)propyl]carbamic acid phenylmethyl ester](/upload/2026/10/5f5fea62418147e49c89dc48958e919d_e3271d9e-3c1a-426e-a6d4-97b0948d3798.png)
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118219-23-1
[(1S)-3-hydroxy-1-(hydroxymethyl)propyl]carbamic acid phenylmethyl ester
-
-
87219-29-2
benzyl (3S)-5-oxotetrahydro-3-furanylcarbamate
-
-
35677-89-5
benzyl (3S)-2-oxotetrahydro-3-furanylcarbamate
| Conditions | Yield |
|---|---|
|
With
1-methyl-1H-imidazole; [2,2]bipyridinyl; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; tetrakis(acetonitrile)copper(I) trifluoromethanesulfonate;
In
acetonitrile;
at 22 ℃;
for 6h;
regioselective reaction;
|
85%
8% |
|
With
1-methyl-1H-imidazole; [2,2]bipyridinyl; tetrakis(acetonitrile)copper(I) trifluoromethanesulfonate; 9-azabicyclo
<3.3.1>
nonane-N-oxyl;
In
acetonitrile;
at 22 ℃;
for 2h;
regioselective reaction;
|
45%
55% |
-
-
57471-70-2
diethyl N-benzyloxycarbonyl-(S)-aspartate
-
-
87219-29-2
benzyl (3S)-5-oxotetrahydro-3-furanylcarbamate
-
-
35677-89-5
benzyl (3S)-2-oxotetrahydro-3-furanylcarbamate
| Conditions | Yield |
|---|---|
|
Multi-step reaction
with
2
steps
1: calcium chloride; sodium tetrahydroborate / tetrahydrofuran; ethanol / 12 h / 25 °C
2: tetrakis(acetonitrile)copper(I) trifluoromethanesulfonate; [2,2]bipyridinyl; 9-azabicyclo
<3.3.1>
nonane-N-oxyl; 1-methyl-1H-imidazole / acetonitrile / 2 h / 22 °C
With
1-methyl-1H-imidazole; [2,2]bipyridinyl; sodium tetrahydroborate; tetrakis(acetonitrile)copper(I) trifluoromethanesulfonate; 9-azabicyclo
<3.3.1>
nonane-N-oxyl; calcium chloride;
In
tetrahydrofuran; ethanol; acetonitrile;
|
87219-29-2 Upstream products
-
133565-44-3
N-benzyloxycarbonyl (S)-β-homoserine benzyl ester
-
4515-23-5
N-benzyloxycarbonyl-L-aspartic acid anhydride
-
57471-70-2
diethyl N-benzyloxycarbonyl-(S)-aspartate
-
1152-61-0
N-Cbz-L-Asp
87219-29-2 Downstream products
-
192517-47-8
methyl (3S)-3-[[(benzyloxy)carbonyl]amino]-4-hydroxybutanoate
-
94718-16-8
(2S,3S)-3-benzyloxycarbonylamino-2-isopropyl-γ-butirolactone
-
152251-84-8
(2S,3S)-3-benzyloxycarbonylamino-2-phenylselenyl-1,4-butyrolactone
-
104227-71-6
N-[(3S)-tetrahydro-5-oxo-3-furanyl]carbamic acid-1,1-dimethylethyl ester
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