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Borane-pyridine complex

  • CAS:110-51-0
  • purity:99%
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1.What is the Borane-pyridine complex ?

Borane-pyridine complex is used for synthesis of α-alkyl-β-hydroxy esters and preparation of Igs conjugated with viral peptide epitopes. It is used as reducing agent for high performance liquid chromatography analysis of oligosaccharides. It is also used as modifier in decant oil affecting its carbonization to mesophase pitch.

pyridine
110-86-1

pyridine

sodium tetrahydroborate
16940-66-2

sodium tetrahydroborate

borane pyridine
110-51-0

borane pyridine

Conditions
Conditions Yield
With iodine; In pyridine; byproducts: NaI, H2; addn. of I2 to Na(BH4) in excess C5H5N, removal of excess C5H5N, extn. of residue with CCl4; evapn.;;
99%
With I2; In pyridine; byproducts: NaI, H2; addn. of I2 to Na(BH4) in excess C5H5N, removal of excess C5H5N, extn. of residue with CCl4; evapn.;;
99%
With ammonium sulfate; In tetrahydrofuran; for 8h; Reflux;
99%
With water; sodium hydrogencarbonate; In tetrahydrofuran; at 20 ℃; for 4h;
99%
With carbon dioxide; In tetrahydrofuran; at 20 ℃; for 0.5h;
99%
With water; sodium hydrogencarbonate; In tetrahydrofuran; at 20 ℃;
93%
In liquid sulphur dioxide; at 0°C;; isolation in soln. by addn. of nitromethane;;
With NH4Cl; In ammonia; NH3 (liquid); addn. of NH4Cl to a soln. of Na(BH4) in liquid NH3, addn. of excess C5H5N, 60°C for 3-4h, addn. of ice, separation of the organic layer, extractn. of aq. phase with ether;; removal of solvent;;
75-80
In sulfur dioxide; at 0°C;; isolation in soln. by addn. of nitromethane;;
With ammonium chloride; In ammonia; addn. of NH4Cl to a soln. of Na(BH4) in liquid NH3, addn. of excess C5H5N, 60°C for 3-4h, addn. of ice, separation of the organic layer, extractn. of aq. phase with ether;; removal of solvent;;
75-80
With sodium hydrogencarbonate; In tetrahydrofuran; water; at 20 ℃; for 4h; Inert atmosphere; Sealed tube;
sodium tetrahydroborate
16940-66-2

sodium tetrahydroborate

pyridine hydrochloride
628-13-7

pyridine hydrochloride

borane pyridine
110-51-0

borane pyridine

Conditions
Conditions Yield
In pyridine; byproducts: NaCl; react. in pyridine (exclusion of H2O); filtration, removal of excess C5H5N in vac. at 50°C, pptn. of excess (C5H5NH)Cl by addn. of ether;; 99.8% purity; (purification also by shaking with H2O);;
87%
In pyridine; byproducts: NaCl; react. in pyridine (exclusion of H2O); filtration, removal of excess C5H5N in vac. at 50°C, pptn. of excess (C5H5NH)Cl by addn. of ether;; 99.8% purity; (purification also by shaking with H2O);;
87%
With 18-crown-6 ether; In diethyl ether; refluxing under Ar for 5 h; cooling, evapn. of solvent, sublimating residue under vac.;
63%

2.What is the CAS number for Borane-pyridine complex ?

The CAS number of Borane-pyridine complex is 110-51-0.

More information of Borane-pyridine complex 110-51-0 are:

CAS?Number

110-51-0

Density

0.92 g/cm3

Melting Point

10-11 °C(lit.)

Boiling Point

1575 ℃

Flash Point

21 °C

Vapor Pressure

22.8mmHg at 25°C

Refractive Index

n20/D 1.532(lit.)

HS CODE

29333990

PSA

3.88000

LogP

-0.89740

3.What are another words for Borane-pyridine complex ?

Synonyms?for?Borane-pyridine complex 110-51-0:Pyridine,compd. with BH3 (1:1) (7CI);Pyridine, compd. with BH3 (6CI);Pyridine, compd.with borane (1:1) (8CI);Borane, compd. with pyridine (1:1) (8CI);Borane-pyridine (1:1);NSC 10219;NSC 53324;Pyridine-borane;Trihydro(pyridine)boron;

4.What is the molecular formula of Borane-pyridine complex?

The chemical formula of ?Borane-pyridine complex is?C5H8BN which containing 5 Carbon atoms,8 Hydrogen atoms,1 Boron atoms and 1 Nitrogen atoms,and the molecular weight of??Borane-pyridine complex?is 92.9362.

5.What is Borane-pyridine complex (110-51-0) used for?

Borane-pyridine complex is a chemical compound consisting of borane (BH3) and pyridine (C5H5N) molecules. It is a colorless to amber liquid with a clear to slightly hazy appearance. This complex is known for its reducing properties and is widely used in various applications across different industries.

InChI:InChI=1/C5H5N.BH3/c1-2-4-6-5-3-1;/h1-5H;1H3

Relevant articles related to Borane-pyridine complex:

Article

Source

Reactions of the Octahydrotriborate(1-) Anion, -, with Some Complexes of Cobalt(I), Cobalt(II), Rhodium(I), and Iridium(I), and the Characterization of the 'Borallyl' Complex III(η3-B3H7)(CO)H(PPh3)2>

Greenwood, Norman N.,Kennedy, John D.,Reed, David

, p. 196 - 200 (1980)

Crown-ether-catalysed synthesis of amine borane and amine trideuterioborane adducts from NaBH4-NaBD4 in ether

Kampel, V.,Warshawsky, A.

, p. 15 - 18 (1994)

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